Green Catalytic Baeyer–Villiger Oxidation with Hydrogen Peroxide in Water Mediated by PtII Catalysts
Alessandra Cavarzan
Dipartimento di Chimica, Università Ca' Foscari di Venezia, Dorsoduro 2137, 30123 Venezia (Italy), Fax: (+399) 041-2348517
Search for more papers by this authorDr. Alessandro Scarso
Dipartimento di Chimica, Università Ca' Foscari di Venezia, Dorsoduro 2137, 30123 Venezia (Italy), Fax: (+399) 041-2348517
Search for more papers by this authorDr. Paolo Sgarbossa
Dipartimento di Processi Chimici dell'Ingegneria, Università di Padova, Via F. Marzolo 9, 35131 Padova (Italy)
Search for more papers by this authorProf. Rino A. Michelin
Dipartimento di Processi Chimici dell'Ingegneria, Università di Padova, Via F. Marzolo 9, 35131 Padova (Italy)
Search for more papers by this authorProf. Giorgio Strukul
Dipartimento di Chimica, Università Ca' Foscari di Venezia, Dorsoduro 2137, 30123 Venezia (Italy), Fax: (+399) 041-2348517
Search for more papers by this authorAlessandra Cavarzan
Dipartimento di Chimica, Università Ca' Foscari di Venezia, Dorsoduro 2137, 30123 Venezia (Italy), Fax: (+399) 041-2348517
Search for more papers by this authorDr. Alessandro Scarso
Dipartimento di Chimica, Università Ca' Foscari di Venezia, Dorsoduro 2137, 30123 Venezia (Italy), Fax: (+399) 041-2348517
Search for more papers by this authorDr. Paolo Sgarbossa
Dipartimento di Processi Chimici dell'Ingegneria, Università di Padova, Via F. Marzolo 9, 35131 Padova (Italy)
Search for more papers by this authorProf. Rino A. Michelin
Dipartimento di Processi Chimici dell'Ingegneria, Università di Padova, Via F. Marzolo 9, 35131 Padova (Italy)
Search for more papers by this authorProf. Giorgio Strukul
Dipartimento di Chimica, Università Ca' Foscari di Venezia, Dorsoduro 2137, 30123 Venezia (Italy), Fax: (+399) 041-2348517
Search for more papers by this authorGraphical Abstract
BV wonder: Baeyer–Villiger oxidation of cyclic ketones with 35 % hydrogen peroxide as a green oxidant mediated by monomeric PtII complexes bearing alkyl diphosphines greatly benefits from the employment of water with anionic surfactants. Under such conditions, the reaction shows enhanced catalytic activity compared to that with organic solvents.
Abstract
Baeyer–Villiger oxidation of cyclic ketones with 35 % hydrogen peroxide as a green oxidant mediated by monomeric PtII complexes bearing alkyl diphosphines greatly benefits from the employment of water with anionic surfactants as reaction medium. Under such conditions, the reaction shows enhanced catalytic activity compared to that with organic solvents. For more acid sensitive substrates, hydrolysis of the lactone product to the corresponding hydroxy acid occurs. Mild experimental conditions, such as moderate temperature and low catalyst loading (≤2 % mol), enabled moderate to good yields.
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