Volume 18, Issue 26 pp. 8000-8003
Communication

MetalMetal Bond Formation Between [n]Metallocenophanes: Synthesis and Characterisation of a Dicarba[2]ruthenocenophanium Dimer

Andrew D. Russell

Andrew D. Russell

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS (UK)

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Dr. Joe B. Gilroy

Dr. Joe B. Gilroy

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS (UK)

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Dr. Kevin Lam

Dr. Kevin Lam

Department of Chemistry, University of Vermont, Burlington, Vermont 05405-0125 (USA)

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Mairi F. Haddow

Mairi F. Haddow

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS (UK)

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Prof. Dr. Jeremy N. Harvey

Corresponding Author

Prof. Dr. Jeremy N. Harvey

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS (UK)

Jeremy N. Harvey, School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS (UK)

William E. Geiger, Department of Chemistry, University of Vermont, Burlington, Vermont 05405-0125 (USA)

Ian Manners, School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS (UK)

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Prof. Dr. William E. Geiger

Corresponding Author

Prof. Dr. William E. Geiger

Department of Chemistry, University of Vermont, Burlington, Vermont 05405-0125 (USA)

Jeremy N. Harvey, School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS (UK)

William E. Geiger, Department of Chemistry, University of Vermont, Burlington, Vermont 05405-0125 (USA)

Ian Manners, School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS (UK)

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Prof. Dr. Ian Manners

Corresponding Author

Prof. Dr. Ian Manners

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS (UK)

Jeremy N. Harvey, School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS (UK)

William E. Geiger, Department of Chemistry, University of Vermont, Burlington, Vermont 05405-0125 (USA)

Ian Manners, School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS (UK)

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First published: 25 May 2012
Citations: 13

Graphical Abstract

Feeling the strain: The first example of metal–metal bonding between strained [n]metallocenophanes is reported. A dicarba[2]ruthenocenophanium dimer has been synthesised through the oxidation of a dicarba[2]ruthenocenophane (see figure). The structural and electrochemical characterisation of the dimer is also discussed.