A Truncated Molecular Star
Soumyakanta Prusty
Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036 India
Search for more papers by this authorDr. Kohei Yazaki
Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036 India
Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503 Japan
Search for more papers by this authorDr. Michito Yoshizawa
Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503 Japan
Search for more papers by this authorCorresponding Author
Prof. Dr. Dillip Kumar Chand
Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036 India
Search for more papers by this authorSoumyakanta Prusty
Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036 India
Search for more papers by this authorDr. Kohei Yazaki
Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036 India
Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503 Japan
Search for more papers by this authorDr. Michito Yoshizawa
Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503 Japan
Search for more papers by this authorCorresponding Author
Prof. Dr. Dillip Kumar Chand
Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036 India
Search for more papers by this authorGraphical Abstract
High five! A star-shaped heteroleptic pentanuclear complex [Pd5(L1)5(L2)5] (BF4)10 was synthesized in a one-pot method, by combining [Pd(DMSO)4](BF4)2 with the non-chelating bidentate ligands 1,4-phenylenebis(methylene) diisonicotinate, L1 and 4,4′-bipyridine, L2 in an equal ratio. The complex is characterized by NMR spectroscopy, MS and single-crystal X-ray diffraction techniques. Interim paths leading to the star were probed to decipher related dynamics of the system.
Abstract
A pentanuclear coordination complex assembled from any palladium(II) component and non-chelating ligands is hitherto unreported. The pentanuclear complex [Pd5(L1)5(L2)5](BF4)10, 1 reported here was prepared by the spontaneous complexation of [Pd(DMSO)4](BF4)2 with the non-chelating bidentate ligands 1,4-phenylenebis(methylene) diisonicotinate, L1 and 4,4′-bipyridine, L2 in a one-pot method at room temperature. The planar polycyclic complex 1 with outer diameters of ≈3 nm is termed as a “molecular star” owing to its resemblance with a pentagram shape. Interim paths leading to the star were also probed to decipher related dynamics of the system.
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References
- 1
- 1aM. Han, D. M. Engelhard, G. H. Clever, Chem. Soc. Rev. 2014, 43, 1848–1860;
- 1bA. Schmidt, A. Casini, F. E. Kühn, Coord. Chem. Rev. 2014, 275, 19–36;
- 1cM. M. J. Smulders, I. A. Riddell, C. Browne, J. R. Nitschke, Chem. Rev. 2013, 42, 1728–1754;
- 1dT. R. Cook, Y.-R. Zheng, P. J. Stang, Chem. Rev. 2013, 113, 734–777;
- 1eN. B. Debata, D. Tripathy, D. K. Chand, Coord. Chem. Rev. 2012, 256, 1831–1945;
- 1hR. Chakrabarty, P. S. Mukherjee, P. J. Stang, Chem. Rev. 2011, 111, 6810–6918.
- 2
- 2aM. L. Saha, S. De, S. Pramanik, M. Schmittel, Chem. Soc. Rev. 2013, 42, 6860–6909;
- 2bM. L. Saha, S. Neogi, M. Schmittel, Dalton Trans. 2014, 43, 3815–3834.
- 3
- 3aD. Preston, J. E. M. Lewis, J. D. Crowley, J. Am. Chem. Soc. 2017, 139, 2379–2386;
- 3bD. Fujita, Y. Ueda, S. Sato, N. Mizuno, T. Kumasaka, M. Fujita, Nature 2016, 540, 563–566;
- 3cK. Yazaki, S. Noda, Y. Tanaka, Y. Sei, M. Akita, M. Yoshizawa, Angew. Chem. Int. Ed. 2016, 55, 15031–15034;
Angew. Chem. 2016, 128, 15255–15258;
10.1002/ange.201608350 Google Scholar
- 3dD. P. August, G. S. Nichol, P. J. Lusby, Angew. Chem. Int. Ed. 2016, 55, 15022–15026;
Angew. Chem. 2016, 128, 15246–15250;
10.1002/ange.201608229 Google Scholar
- 3eP. Howlader, P. S. Mukherjee, Chem. Sci. 2016, 7, 5893–5899;
- 3fM. Krick, J. Holstein, C. Würtele, G. H. Clever, Chem. Commun. 2016, 52, 10411–10414;
- 3gS. Bandi, D. K. Chand, Chem. Eur. J. 2016, 22, 10330–10335.
- 4
- 4aM. Han, Y. Luo, B. Damaschke, L. Gómez, X. Ribas, A. Jose, P. Peretzki, M. Seibt, G. H. Clever, Angew. Chem. Int. Ed. 2016, 55, 445–449;
Angew. Chem. 2016, 128, 456–460;
10.1002/ange.201508307 Google Scholar
- 4bS. Ganta, D. K. Chand, Dalton Trans. 2015, 44, 15181–15188;
- 4cD. Samanta, P. S. Mukherjee, Chem. Eur. J. 2014, 20, 12483–12492;
- 4dD. M. Engelhard, S. Freye, K. Grohe, M. John, G. H. Clever, Angew. Chem. Int. Ed. 2012, 51, 4747–4750;
Angew. Chem. 2012, 124, 4828–4832;
10.1002/ange.201200611 Google Scholar
- 4eK. Umakoshi, Y. Yamauchi, K. Nakamiya, T. Kojima, M. Yamasaki, H. Kawano, M. Onishi, Inorg. Chem. 2003, 42, 3907–3916;
- 4fP. Baran, C. M. Marrero, S. Pérez, R. G. Raptis, Chem. Commun. 2002, 9, 1012–1013.
- 5
- 5aW. M. Bloch, Y. Abe, J. J. Holstein, C. M. Wandtke, B. Dittrich, G. H. Clever, J. Am. Chem. Soc. 2016, 138, 13750–13755;
- 5bK. Suzuki, M. Kawano, M. Fujita, Angew. Chem. Int. Ed. 2007, 46, 2819–2822;
Angew. Chem. 2007, 119, 2877–2880;
10.1002/ange.200605084 Google Scholar
- 5cD. K. Chand, K. Biradha, M. Kawano, S. Sakamoto, K. Yamaguchi, M. Fujita, Chem. Asian J. 2006, 1–2, 82–90.
- 6
- 6aP. Howlader, S. Mukherjee, R. Sahab, P. S. Mukherjee, Dalton Trans. 2015, 44, 20493–20501;
- 6bM. Han, R. Michel, G. H. Clever, Chem. Eur. J. 2014, 20, 10640–10644;
- 6cK. Suzuki, M. Tominaga, M. Kawano, M. Fujita, Chem. Commun. 2009, 1638–1640.
- 7D. Fujita, H. Yokoyama, Y. Ueda, S. Sato, M. Fujita, Angew. Chem. Int. Ed. 2015, 54, 155–158;
Angew. Chem. 2015, 127, 157–160.
10.1002/ange.201409216 Google Scholar
- 8
- 8aQ.-F. Sun, J. Iwasa, D. Ogawa, Y. Ishido, S. Sato, T. Ozeki, Y. Sei, K. Yamaguchi, M. Fujita, Science 2010, 328, 1144–1147;
- 8bM. Tominaga, K. Suzuki, T. Murase, M. Fujita, J. Am. Chem. Soc. 2005, 127, 11950–11951;
- 8cM. Tominaga, K. Suzuki, M. Kawano, T. Kusukawa, T. Ozeki, S. Sakamoto, K. Yamaguchi, M. Fujita, Angew. Chem. Int. Ed. 2004, 43, 5621–5625;
Angew. Chem. 2004, 116, 5739–5743.
10.1002/ange.200461422 Google Scholar
- 9D. Fujita, Y. Ueda, S. Sato, H. Yokoyama, N. Mizuno, T. Kumasaka, M. Fujita, Chem 2016, 1, 91–101.
- 10
- 10aS. Bandi, S. Samantray, R. D. Chakravarthy, A. K. Pal, G. S. Hanan, D. K. Chand, Eur. J. Inorg. Chem. 2016, 2816–2827;
- 10bM. D. Johnstone, E. K. Schwarze, G. H. Clever, F. M. Pfeffer, Chem. Eur. J. 2015, 21, 3948–3955;
- 10cS. Bandi, A. K. Pal, G. S. Hanan, D. K. Chand, Chem. Eur. J. 2014, 20, 13122–13126.
- 11
- 11aB. Roy, E. Zangrandob, P. S. Mukherjee, Chem. Commun. 2016, 52, 4489–4492;
- 11bJ. J. Henkelis, J. Fisher, S. L. Warriner, M. J. Hardi, Chem. Eur. J. 2014, 20, 4117–4125;
- 11cC.-W. Zhao, J.-P. Ma, Q.-K. Liu, Y. Yu, P. Wang, Y.-A. Li, K. Wang, Y.-B. Dong, Green Chem. 2013, 15, 3150–3315;
- 11dS. Ghosh, P. S. Mukherjee, J. Org. Chem. 2006, 71, 8412–8416;
- 11eD. K. Chand, K. Biradha, M. Fujita, S. Sakamotob, K. Yamaguchi, Chem. Commun. 2002, 2486–2487.
- 12Q.-F. Sun, S. Sato, M. Fujita, Nat. Chem. 2012, 4, 330–333.
- 13Q.-F. Sun, T. Murase, S. Sato, M. Fujita, Angew. Chem. Int. Ed. 2011, 50, 10318–11325;
Angew. Chem. 2011, 123, 10502–10505.
10.1002/ange.201104670 Google Scholar
- 14I. A. Bhat, D. Samanta, P. S. Mukherjee, J. Am. Chem. Soc. 2015, 137, 9497–9502.
- 15A. M. Johnson, R. J. Hooley, Inorg. Chem. 2011, 50, 4671–4673.
- 16
- 16aD. Preston, J. E. Barnsley, K. C. Gordon, J. D. Crowley, J. Am. Chem. Soc. 2016, 138, 10578–10585;
- 16bM. Yamashina, T. Yuki, Y. Sei, M. Akita, M. Yoshizawa, Chem. Eur. J. 2015, 21, 4200–4204.
- 17P. Howlader, P. Das, E. Zangrando, P. S. Mukherjee, J. Am. Chem. Soc. 2016, 138, 1668–1676.
- 18Q.-F. Sun, S. Sato, M. Fujita, Angew. Chem. Int. Ed. 2014, 53, 13510–13513;
Angew. Chem. 2014, 126, 13728–13731.
10.1002/ange.201408652 Google Scholar
- 19
- 19aH. Lee, T. H. Noh, O.-S. Jung, Angew. Chem. Int. Ed. 2016, 55, 1005–1009;
Angew. Chem. 2016, 128, 1017–1021;
10.1002/ange.201509485 Google Scholar
- 19bH. Lee, T. H. Noh, O.-S. Jung, Angew. Chem. Int. Ed. 2013, 52, 11790–11795;
Angew. Chem. 2013, 125, 12006–12011.
10.1002/ange.201306674 Google Scholar
- 20B. F. G. Johnson, J. Puga, P. R. Raithby, Acta Crystallogr. Sect. B 1981, 37, 953–956.
- 21S. Prusty, S. Krishnaswamy, S. Bandi, B. Chandrika, J. Luo, J. S. McIndoe, G. S. Hanan, D. K. Chand, Chem. Eur. J. 2015, 21, 15174–15187.
- 22M. Fujita, J. Yazaki, K. Ogura, J. Am. Chem. Soc. 1990, 112, 5645–5647.
- 23
- 23aK. Uehara, K. Kasai, N. Mizuno, Inorg. Chem. 2007, 46, 2563–2570;
- 23bM. Fujita, O. Sasaki, T. Mitsuhashi, T. Fujita, J. Yazaki, K. Yamaguchi, K. Ogura, Chem. Commun. 1996, 1535–1536.
- 24Recent examples:
- 24aH. Sepehrpour, M. L. Saha, P. J. Stang, J. Am. Chem. Soc. 2017, 139, 2553–2556;
- 24bS.-Y. Wang, J.-H. Fu, Y.-P. Liang, Y.-J. He, Y.-S. Chen, Y.-T. Chan, J. Am. Chem. Soc. 2016, 138, 3651–3654;
- 24cT. K. Ronson, D. A. Roberts, S. P. Black, J. R. Nitschke, J. Am. Chem. Soc. 2015, 137, 14502–14512;
- 24dJ. Yang, M. Bhadbhade, W. A. Donald, H. Iranmanesh, E. G. Moore, H. Yana, J. E. Beves, Chem. Commun. 2015, 51, 4465–4468.
- 25
- 25aB. Hasenknopf, J.-M. Lehn, B. O. Kneisel, G. Baum, D. Fenske, Angew. Chem. Int. Ed. Engl. 1996, 35, 1838–1840; Angew. Chem. 1996, 108, 1987–1990;
- 25bD. A. Leigh, R. G. Pritchard, A. J. Stephens, Nat. Chem. 2014, 6, 978–982.
- 26D. Kumar Chand, M. Fujita, K. Biradha, S. Sakamoto, K. Yamaguchi, Dalton Trans. 2003, 2750–2756.
