Dichloro-Cycloazatriphosphane: The Missing Link between N2P2 and P4 Ring Systems in the Systematic Development of NP Chemistry
Dr. Jonas Bresien
Institut für Chemie, Universität Rostock, Albert-Einstein-Straße 3a, 18059 Rostock, Germany
Search for more papers by this authorDr. Alexander Hinz
Department of Chemistry, University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford, OX1 3TA UK
Search for more papers by this authorCorresponding Author
Prof. Dr. Axel Schulz
Institut für Chemie, Universität Rostock, Albert-Einstein-Straße 3a, 18059 Rostock, Germany
Leibniz-Institut für Katalyse an der Universität Rostock e.V., Albert-Einstein-Straße 29a, 18059 Rostock, Germany
Search for more papers by this authorTim Suhrbier
Institut für Chemie, Universität Rostock, Albert-Einstein-Straße 3a, 18059 Rostock, Germany
Search for more papers by this authorMax Thomas
Institut für Chemie, Universität Rostock, Albert-Einstein-Straße 3a, 18059 Rostock, Germany
Search for more papers by this authorDr. Alexander Villinger
Institut für Chemie, Universität Rostock, Albert-Einstein-Straße 3a, 18059 Rostock, Germany
Search for more papers by this authorDr. Jonas Bresien
Institut für Chemie, Universität Rostock, Albert-Einstein-Straße 3a, 18059 Rostock, Germany
Search for more papers by this authorDr. Alexander Hinz
Department of Chemistry, University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford, OX1 3TA UK
Search for more papers by this authorCorresponding Author
Prof. Dr. Axel Schulz
Institut für Chemie, Universität Rostock, Albert-Einstein-Straße 3a, 18059 Rostock, Germany
Leibniz-Institut für Katalyse an der Universität Rostock e.V., Albert-Einstein-Straße 29a, 18059 Rostock, Germany
Search for more papers by this authorTim Suhrbier
Institut für Chemie, Universität Rostock, Albert-Einstein-Straße 3a, 18059 Rostock, Germany
Search for more papers by this authorMax Thomas
Institut für Chemie, Universität Rostock, Albert-Einstein-Straße 3a, 18059 Rostock, Germany
Search for more papers by this authorDr. Alexander Villinger
Institut für Chemie, Universität Rostock, Albert-Einstein-Straße 3a, 18059 Rostock, Germany
Search for more papers by this authorGraphical Abstract
NP3 ring system: Starting from a highly reactive amino-diphosphene, a dichloro-cycloazatriphosphane (see Scheme) could be synthesized and fully characterized. This new ring system can be regarded as a congener of [XP(μ-NR)]2 and [XP(μ-PR)]2 systems and therefore contributes to a systematic development of NP chemistry.
Abstract
A dichloro-cycloazatriphosphane that incorporates a cyclic NP3 backbone could be synthesized using knowledge gained from the chemistry of N2P2 and P4 ring systems. It fills the gap between the congeneric compounds [ClP(μ-NR)]2 and [ClP(μ-PR)]2 (R=sterically demanding substituent), and thus contributes to the systematic development of nitrogen–phosphorus chemistry in general. The title compound was studied with respect to its formation via a labile aminodiphosphene, which readily underwent different rearrangement reactions depending on the solvent. All compounds were fully characterized by experimental and computational methods.
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