Volume 29, Issue 35 e202301522
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Front Cover: Deoxygenative Radical Boration of Inert Amides via a Combination of Relay and Cooperative Catalysis (Chem. Eur. J. 35/2023)

Dr. Feng Jiang

Dr. Feng Jiang

School of Chemistry and Materials Science, Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, 1 Sub-lane Xiangshan, Hangzhou, 310024 China

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032 (China).

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Jing'an Li

Jing'an Li

School of Chemistry and Materials Science, Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, 1 Sub-lane Xiangshan, Hangzhou, 310024 China

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032 (China).

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Prof. Xiaoming Wang

Corresponding Author

Prof. Xiaoming Wang

School of Chemistry and Materials Science, Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, 1 Sub-lane Xiangshan, Hangzhou, 310024 China

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032 (China).

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First published: 25 May 2023

Graphical Abstract

From substrates to products. Just as boats make crossing from one side of a river to the other possible, a suitable catalytic system allows access to difficult or unattainable transformations. An unprecedented reductive boration of amides is achieved through a triple iridium–photoredox–organocatalysis system, affording valuable α-amino boron products. More information can be found in the Research Article by X. Wang and co-workers (DOI: 10.1002/chem.202301199).