Volume 29, Issue 37 e202301587
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Front Cover: Direct C−H Arylation of Dithiophene-Tetrathiafulvalene: Tuneable Electronic Properties and 2D Self-Assembled Molecular Networks at the Solid/Liquid Interface (Chem. Eur. J. 37/2023)

Catarina Ribeiro

Catarina Ribeiro

Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, Campus de Santiago, Aveiro, 3810-393 Portugal

These authors contributed equally to this work.

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Gonçalo Valente

Gonçalo Valente

Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, Campus de Santiago, Aveiro, 3810-393 Portugal

These authors contributed equally to this work.

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Dr. Miguel Espinosa

Dr. Miguel Espinosa

Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, Campus de Santiago, Aveiro, 3810-393 Portugal

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Dr. Rafaela A. L. Silva

Dr. Rafaela A. L. Silva

Centro de Ciências e Tecnologias Nucleares, Instituto Superior Técnico, Universidade de Lisboa, Portugal, E.N. 10, P-2695-066 Bobadela LRS, Portugal

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Dr. Dulce Belo

Dr. Dulce Belo

Centro de Ciências e Tecnologias Nucleares, Instituto Superior Técnico, Universidade de Lisboa, Portugal, E.N. 10, P-2695-066 Bobadela LRS, Portugal

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Dr. Sara Gil-Guerrero

Dr. Sara Gil-Guerrero

Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, Campus de Santiago, Aveiro, 3810-393 Portugal

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Dr. Nicolás Arisnabarreta

Dr. Nicolás Arisnabarreta

Department of Chemistry, Division of Molecular Imaging and Photonics, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium

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Dr. Kunal S. Mali

Dr. Kunal S. Mali

Department of Chemistry, Division of Molecular Imaging and Photonics, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium

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Prof. Steven De Feyter

Prof. Steven De Feyter

Department of Chemistry, Division of Molecular Imaging and Photonics, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium

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Dr. Manuel Melle-Franco

Dr. Manuel Melle-Franco

Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, Campus de Santiago, Aveiro, 3810-393 Portugal

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Dr. Manuel Souto

Corresponding Author

Dr. Manuel Souto

Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, Campus de Santiago, Aveiro, 3810-393 Portugal

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First published: 30 May 2023

Graphical Abstract

Synthesis of a new family of arylated dithiophene-tetrathiafulvalene (DT-TTF) derivatives. The influence of electron-donating and electron-withdrawing substituents on DT-TTF's electronic properties has been evaluated. Two-dimensional, hydrogen-bonded, self-assembled networks of tetrabenzoic acid derivative at the graphite/liquid interface were visualized by scanning tunneling microscopy. More information can be found in the Research Article by M. Souto and co-workers (DOI: 10.1002/chem.202300572).