Photochemical Water Oxidation Catalyzed by a Water-Soluble Copper Phthalocyanine Complex
Ryota Terao
Department of Chemistry, Faculty of Sciences, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka, 812-8581 Japan
Search for more papers by this authorTakashi Nakazono
Department of Chemistry, Faculty of Sciences, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka, 812-8581 Japan
International Institute for Carbon–Neutral Energy Research (WPI-I2CNER), Kyushu University, Motooka 744, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorCorresponding Author
Dr. Alexander Rene Parent
International Institute for Carbon–Neutral Energy Research (WPI-I2CNER), Kyushu University, Motooka 744, Nishi-ku, Fukuoka, 819-0395 Japan
Department of Chemistry and Biochemistry, North Dakota State University, PO Box 6050, Fargo, ND, 58108-6050 USA
Search for more papers by this authorCorresponding Author
Prof. Ken Sakai
Department of Chemistry, Faculty of Sciences, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka, 812-8581 Japan
International Institute for Carbon–Neutral Energy Research (WPI-I2CNER), Kyushu University, Motooka 744, Nishi-ku, Fukuoka, 819-0395 Japan
Center for Molecular Systems (CMS), Kyushu University, Motooka 744, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorRyota Terao
Department of Chemistry, Faculty of Sciences, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka, 812-8581 Japan
Search for more papers by this authorTakashi Nakazono
Department of Chemistry, Faculty of Sciences, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka, 812-8581 Japan
International Institute for Carbon–Neutral Energy Research (WPI-I2CNER), Kyushu University, Motooka 744, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorCorresponding Author
Dr. Alexander Rene Parent
International Institute for Carbon–Neutral Energy Research (WPI-I2CNER), Kyushu University, Motooka 744, Nishi-ku, Fukuoka, 819-0395 Japan
Department of Chemistry and Biochemistry, North Dakota State University, PO Box 6050, Fargo, ND, 58108-6050 USA
Search for more papers by this authorCorresponding Author
Prof. Ken Sakai
Department of Chemistry, Faculty of Sciences, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka, 812-8581 Japan
International Institute for Carbon–Neutral Energy Research (WPI-I2CNER), Kyushu University, Motooka 744, Nishi-ku, Fukuoka, 819-0395 Japan
Center for Molecular Systems (CMS), Kyushu University, Motooka 744, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorGraphical Abstract
En route to solar fuels: Copper tetrasulfonatophthalocyanine serves as a water oxidation catalyst in the photoreaction using Ru(bpy)32+/Na2S2O8. (bpy=2,2′-bipyridine; see figure). Kinetic studies indicate a bimolecular radical coupling process to be the rate-determining step. Chloride contamination was found to dramatically decrease the water oxidation rate.
Abstract
Copper tetrasulfonatophthalocyanine (CuPcTS) is reported to serve as a catalyst for photochemical water oxidation via a radical coupling mechanism. Chloride greatly inhibits the water oxidation rate as a result of axial chloride binding to CuPcTS, preventing formation of the Cu oxyl or hydroxyl intermediate required for O−O bond formation.
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