Ligand Self-Sorting and Nonlinear Effects in Dinuclear Asymmetric Hydrogenation: Complexity in Catalysis
Frédéric G. Terrade
Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam (The Netherlands), Fax: (+31) 205255604
Search for more papers by this authorDr. Martin Lutz
Crystal and Structural Chemistry, Bijvoet Center for Biomolecular Research, Utrecht University, Padualaan 8, 3584 CH Utrecht (The Netherlands)
Search for more papers by this authorCorresponding Author
Prof. Dr. Joost N. H. Reek
Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam (The Netherlands), Fax: (+31) 205255604
Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam (The Netherlands), Fax: (+31) 205255604Search for more papers by this authorFrédéric G. Terrade
Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam (The Netherlands), Fax: (+31) 205255604
Search for more papers by this authorDr. Martin Lutz
Crystal and Structural Chemistry, Bijvoet Center for Biomolecular Research, Utrecht University, Padualaan 8, 3584 CH Utrecht (The Netherlands)
Search for more papers by this authorCorresponding Author
Prof. Dr. Joost N. H. Reek
Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam (The Netherlands), Fax: (+31) 205255604
Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam (The Netherlands), Fax: (+31) 205255604Search for more papers by this authorGraphical Abstract
Self-sorting species: Nonlinear effects are observed in asymmetric hydrogenation reactions if self-sorted dinuclear complexes are generated. The nature of the substrate also influences this effect, because it affects the solubility of racemic self-sorted homochiral dinuclear complexes (see scheme).
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