Reactions of Diaryldibromodisilenes with N‐Heterocyclic Carbenes: Formation of Formal Bis‐NHC Adducts of Silyliumylidene Cations
Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Kyoto University Pioneering Research Unit for Next Generation, Gokasho Uji, Kyoto 611‐0011 (Japan)
Search for more papers by this authorDepartment of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3‐4‐1 Kowakae, Higashi‐Osaka 577‐8502 (Japan)
Search for more papers by this authorCorresponding Author
Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Takahiro Sasamori, Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Tsukasa Matsuo, Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3‐4‐1 Kowakae, Higashi‐Osaka 577‐8502 (Japan)
Norihiro Tokitoh, Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Search for more papers by this authorCorresponding Author
Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3‐4‐1 Kowakae, Higashi‐Osaka 577‐8502 (Japan)
JST, PRESTO, 4‐1‐8 Honcho Kawaguchi, Saitama 332‐0012 (Japan)
Takahiro Sasamori, Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Tsukasa Matsuo, Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3‐4‐1 Kowakae, Higashi‐Osaka 577‐8502 (Japan)
Norihiro Tokitoh, Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Search for more papers by this authorMaterials Characterization Support Unit, RIKEN Center for Emergent Matter Science, 2‐1 Hirosawa, Wako, Saitama 351‐0198 (Japan)
Search for more papers by this authorCorresponding Author
Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Takahiro Sasamori, Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Tsukasa Matsuo, Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3‐4‐1 Kowakae, Higashi‐Osaka 577‐8502 (Japan)
Norihiro Tokitoh, Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Search for more papers by this authorInstitute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Kyoto University Pioneering Research Unit for Next Generation, Gokasho Uji, Kyoto 611‐0011 (Japan)
Search for more papers by this authorDepartment of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3‐4‐1 Kowakae, Higashi‐Osaka 577‐8502 (Japan)
Search for more papers by this authorCorresponding Author
Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Takahiro Sasamori, Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Tsukasa Matsuo, Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3‐4‐1 Kowakae, Higashi‐Osaka 577‐8502 (Japan)
Norihiro Tokitoh, Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Search for more papers by this authorCorresponding Author
Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3‐4‐1 Kowakae, Higashi‐Osaka 577‐8502 (Japan)
JST, PRESTO, 4‐1‐8 Honcho Kawaguchi, Saitama 332‐0012 (Japan)
Takahiro Sasamori, Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Tsukasa Matsuo, Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3‐4‐1 Kowakae, Higashi‐Osaka 577‐8502 (Japan)
Norihiro Tokitoh, Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Search for more papers by this authorMaterials Characterization Support Unit, RIKEN Center for Emergent Matter Science, 2‐1 Hirosawa, Wako, Saitama 351‐0198 (Japan)
Search for more papers by this authorCorresponding Author
Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Takahiro Sasamori, Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Tsukasa Matsuo, Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3‐4‐1 Kowakae, Higashi‐Osaka 577‐8502 (Japan)
Norihiro Tokitoh, Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611‐0011 (Japan), Fax: (+81) 774‐3209
Search for more papers by this authorAbstract
Reactions of stable 1,2‐dibromodisilenes ((E)‐Ar(Br)SiSi(Br)Ar) with N‐heterocyclic carbenes (NHC) afforded NHC–arylbromosilylene adducts or bromide salts of the corresponding bis‐NHC adducts of the formal arylsilyliumylidene cations ([ArSi:]+). In some cases, an NHC was able to replace a bromide anion in the coordination sphere of the arylbromosilylene–NHC adduct.
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