Volume 21, Issue 14
Frontispiece

Frontispiece: Supramolecular Interaction of Fullerenes with a Curved π‐Surface of a Monomeric Quadruply Ring‐Fused Porphyrin

Yuta Saegusa

Department of Chemistry, University of Tsukuba, 1‐1‐1 Tennoudai, Tsukuba, Ibaraki 305‐8571 (Japan)

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Dr. Tomoya Ishizuka

Corresponding Author

Department of Chemistry, University of Tsukuba, 1‐1‐1 Tennoudai, Tsukuba, Ibaraki 305‐8571 (Japan)

Department of Chemistry, University of Tsukuba, 1‐1‐1 Tennoudai, Tsukuba, Ibaraki 305‐8571 (Japan)Search for more papers by this author
Dr. Tatsuhiro Kojima

Division of Advanced Materials Science, Pohang University of Science and Technology (POSTECH), San 31, Hyoja‐dong, Pohang, 790‐784 (Korea)

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Dr. Shigeki Mori

Department of Molecular Science, Integrated Center for Science, Ehime University, Matsuyama 790‐8577 (Japan)

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Prof. Dr. Masaki Kawano

Division of Advanced Materials Science, Pohang University of Science and Technology (POSTECH), San 31, Hyoja‐dong, Pohang, 790‐784 (Korea)

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Prof. Dr. Takahiko Kojima

Corresponding Author

Department of Chemistry, University of Tsukuba, 1‐1‐1 Tennoudai, Tsukuba, Ibaraki 305‐8571 (Japan)

Department of Chemistry, University of Tsukuba, 1‐1‐1 Tennoudai, Tsukuba, Ibaraki 305‐8571 (Japan)Search for more papers by this author
First published: 18 March 2015

Abstract

Fullerenes Supramolecular complexation of fullerenes with a monomeric zinc(II) complex of a ring‐fused porphyrin derivative, having a concave π‐conjugated surface induced by the axial coordination of pyridine, has been confirmed by spectroscopic measurements and X‐ray diffraction analysis, as discussed by T. Ishizuka, T. Kojima et al. in their Communication on page 5302 ff. Shape matching between fullerenes and the porphyrin is shown to be crucial for the strong interaction.